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1690 ca. 1620 ca. 1675 ca. 1635 ca. 3000 1700-1680 ca. 1360 600-580 1275-1250 ca. 1690 ca. 3280 1670-1650 ca. 1275 ca. 640 1680-1655 915-900 865-825 860-800 920-895 1680-1650 ca. 3410 ca. 3300 ca. 1600 ca. 3450 ca. 1630 Intensity VW VS w-m m-s W VS VS VS VS S VS S VW-W VS S S S VS VW VS S S VS w-m m-s S S VS m m S vwvbr S Remark First star tattoo galleries Acetyl band Also with aldehydes Derivatives Derivatives Derivatives Acetyl band First star tattoo galleries Sometimes split Multiply split Split Table 3. 11 Characteristic absorption band combinations/partial spectra of CHO-carbonyl compounds: aldehydes, carboxylic acids, carboxylates Vibrating group Aliphatic-CHO saturated Assignment 2xv(C=0) v(C-H) V(C=O) 6(CH2-CO) Range/cm"1 ca. 3430 2845-2820 2735-2720 1730-1720 ca. 1410 Intensity vw sh m m VS W Remark First star tattoo galleries Fermi resonance Broader than v(CH2) Table 3. 11 Contunie Vibrating group conjug. -unsat. Aromatic-CHO Aliphatic-COOH saturated conj. unsatur. Aromatic-COOH Carboxylates aliphatic -CO2" edingurgh tattoo sydney -CO2" Assignment 2x V(C=O) v(C-H) V(C=O) V(C=C) v(C-H) V(C=O) v(ring-C) Range/cm"1 3370-3320 2845-2780 2755-2700 1695-1680 1640-1615 2865-2820 2760-2720 1705-1695 ca. 1200 Intensity vw sh W VW-W VS s sh W wsh VS m-s sh All bands of the 8-memb. ring of dimers are broad v(0H)free v(0H)ass. V(C=O) v(C0)6(0H) y(O-H. . . O) V(C=O) V(C=C) v(0H)ass. V(C=O) v(C0)6(0H) y(O-H. . . O) Va8(CO2) V8(CO2) 6(CO2) Vas(CO2) V8(CO2) 3580-3500 3400-2500 2700-2500 ca. 1710 ca. 1410 ca. 950 1705-1690 1650-1635 3150-2500 ca. 2650 2550-2520 1690-1680 1420-1400 940-905 1560-1520 ca. 1425 ca. 700 1565-1530 1390-1360 m s vbr w-mbr VS w-m mbr VS S mbr mbr mbr VSt m-s m-sbr VS w-mbr w-m VS S-VS Remark First star tattoo galleries Fermi resonance Additl. weak bands in this range Not always present Dilute solution Overlappg. of several H-bond species Two bds. of defin. associates Medium broad Combination band E-configuration Intensif. by conj. Mult, overlapping bands Denned Associates Combination band Sometimes split Sometimes split Red flank of 9(CH2)n Table 3.


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